Peep Boy at npc (Fallout 4)

Spoiler In order to see the things of the companion, including those worn, you need to select it in the console and enter showinventory or inv, where you can see the ID of the required item. The command to remove an item: removeitem xy, where x is the BaseID of the item, y is the amount. There are also commands that allow you to forcibly equip an item to a companion or also remove it: equipitem x and unequipitem x, where x is the BaseID of the item.
an extreme case - NPC Editor

Thanks. helped)) !!!